Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Electro Chemistry

Question:

How much charge is required for the reduction of \(0.05\) moles of \(MnO_4^-\) to \(MnO_2\)?

Options:

\(5 × 96500 × 0.05 C\)

\(3 × 96500 × 0.05 C\)

\(1 × 96500 × 0.05 C\)

\(2 × 96500 × 0.05 C\)

Correct Answer:

\(3 × 96500 × 0.05 C\)

Explanation:

The correct answer is option 2. \(3 × 96500 × 0.05 C\).

The reaction can be written as:

\(MnO_4^- + 8H^+ + 5e^- \longrightarrow MnO_2 + 4H_2O\)

The oxidation state of Mn on the left hand side of the equation is +7, and it is +2 on the right hand side.

Thus, it is being reduced by 5 units of electrons to achieve the new oxidation state

So, we see that 5 moles of electrons are required to reduce 1 mole \(MnO_4^-\)

1 mole of electrons carries 3 Faraday, or 96,500 C charge.

So, 0.05 moles of electrons will carry \(3 × 96,500 × 0.05 C\)