Practicing Success
Increasing order of oxidation states of transition metal oxides will be: (A) \(TiO_2\) (B) \(MnO_4 ^-\) (C) \(VO_2^+\) (D) \(CrO_4^{2-}\) (E) \(Ni(CO)_4\) Choose the correct answer from the options given below: |
(B) < (D) < (C) < (A) < (E) (E) < (C) < (A) < (D) < (B) (E) < (A) < (C) < (D) < (B) (B) < (A) < (C) < (D) < (E) |
(E) < (C) < (A) < (D) < (B) |
The correct answer is option 2. (E) < (C) < (A) < (D) < (B). Let us explain the order of oxidation states for each compound: (E) \(Ni(CO)_4\) - In tetracarbonylnickel(0) (\(Ni(CO)_4\)), nickel (Ni) has an oxidation state of 0. Carbon monoxide (CO) is a neutral ligand, so it does not affect the oxidation state of nickel. (C) \(VO_2^+\) - In vanadium dioxide ion (\(VO_2^+\)), vanadium (V) has an oxidation state of +4. This is because oxygen usually has an oxidation state of -2, and the overall charge of the ion is +1. (A) \(TiO_2\) - Titanium dioxide (\(TiO_2\)) consists of titanium (Ti) with an oxidation state of +4. This is a common oxidation state for titanium in its compounds. (D) \(CrO_4^{2-}\) - In chromate ion (\(CrO_4^{2-}\)), chromium (Cr) has an oxidation state of +6. Each oxygen atom has an oxidation state of -2, and the overall charge of the ion is -2. (B) \(MnO_4^-\) - Permanganate ion (\(MnO_4^-\)) contains manganese (Mn) with an oxidation state of +7. Each oxygen atom has an oxidation state of -2, and the overall charge of the ion is -1. Arranging them in increasing order of oxidation states: \(E < C < A < D < B\) Therefore, the correct order is: 2. (E) < (C) < (A) < (D) < (B) |