The first headmistress of the country's first school for girls in Pune was:-

Savitri Bai Phule

The correct answer is Option 1: Savitri Bai Phule

Savitri Bai Phule was the first headmistress of the country’s first school for girls in Pune. She devoted her life to educating Shudras and Ati-Shudras. She started a night school for agriculturists and labourers. She died while serving plague patients.