Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: D and F Block Elements

Question:

\(Mn_2O_7, CrO\) and \(V_2O_5\) respectively are:

Options:

Acidic, amphoteric, and basic

Basic, acidic, and amphoteric

Amphoteric, basic, and acid

Acidic, basic and amphoteric

Correct Answer:

Acidic, basic and amphoteric

Explanation:

The correct answer is (4) Acidic, basic, and amphoteric.

1. \(Mn_2O_7\) (Manganese Heptoxide):
\(Mn_2O_7\) is an oxide of manganese. In this compound, each manganese atom is in the +7 oxidation state. It's important to note that the oxidation state of the metal in an oxide can give us clues about its acidic or basic properties.

  • Manganese (Mn) in \(Mn_2O_7\) is in a high oxidation state (+7).
  • High oxidation state metals tend to form acidic oxides.

So, \(Mn_2O_7\) is acidic because it can release hydrogen ions (\(H^+\)) when dissolved in water, making it an acid.

2. \(CrO\) (Chromium(II) Oxide):
\(CrO\) is an oxide of chromium. In this compound, each chromium atom is in the +2 oxidation state. Again, let's consider the oxidation state of the metal to determine its properties.

  • Chromium (Cr) in \(CrO\) is in a low oxidation state (+2).
  • Low oxidation state metals tend to form basic oxides.

So, \(CrO\) is basic because it can accept hydrogen ions (\(H^+\)) when dissolved in water, making it a base.

3. \(V_2O_5\) (Vanadium Pentoxide):
\(V_2O_5\) is an oxide of vanadium. In this compound, each vanadium atom is in the +5 oxidation state. As before, let's consider the oxidation state of the metal.

  • Vanadium (V) in \(V_2O_5\) is in an intermediate oxidation state (+5).
  • Intermediate oxidation-state metals can exhibit amphoteric behavior. Amphoteric compounds can act as both acids and bases depending on the conditions.

So, \(V_2O_5\) is amphoteric because it can either donate or accept hydrogen ions (\(H^+\)) depending on the pH of the solution in which it's dissolved.

In summary:

  • \(Mn_2O_7\) is acidic due to the high oxidation state of manganese.
  • \(CrO\) is basic due to the low oxidation state of chromium.
  • \(V_2O_5\) is amphoteric due to the intermediate oxidation state of vanadium.