Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Alcohols, Phenols and Ethers

Question:

An organic compound A having molecular formula C6H6O gives a violet colour with neutral FeCl3 ​ solution. A on treatment with CO2​ and NaOH at 400 K under pressure gives B which on acidification gives a compound C. The compound C reacts with acetyl chloride to give D which is popular pain killer. Deduce the structure of A, B, C and D.

What is the name of conversion of compound A to compound C?

Options:

Reimer-Tiemann reaction

Kolbe's reaction

Schimdt reaction

Swarts reaction

Correct Answer:

Kolbe's reaction

Explanation:

The correct answer is option 2.Kolbe's reaction.

The conversion of compound A (phenol) to compound C (salicylic acid) involves the reaction of phenol with COâ‚‚ and NaOH under pressure and elevated temperature, followed by acidification. This reaction is known as Kolbe's reaction.