Complete the following reaction: \(2H_2O + 5SO_2 + 2MNO_4^- \longrightarrow _{------} + _{------} + _{------}\) |
\(5SO_4^{2-}, \, \ 4H^+, \, \ 2Mn^{2+}\) \(5SO_3^{2-}, \, \ 4OH^-, \, \ 2Mn^{2+}\) \(5SO_4^{2-}, \, \ 4H^+, \, \ 2Mn^{3+}\) \(5S_2O_3^{2-}, \, \ 4H^+, \, \ 2MnO_2\) |
\(5SO_4^{2-}, \, \ 4H^+, \, \ 2Mn^{2+}\) |
The correct answer is option 1. \(5SO_4^{2-}, \, \ 4H^+, \, \ 2Mn^{2+}\). Let us analyze the reaction and identify the products step by step. The given reaction is: \( 2H_2O + 5SO_2 + 2MnO_4^- \longrightarrow \text{Products} \) Step 1: Identify the Oxidation and Reduction Processes Sulfur Dioxide (SO\(_2\)): Oxidation: Sulfur in SO\(_2\) has an oxidation state of +4. Products: Upon oxidation, SO\(_2\) is likely converted to sulfate ion \((SO_4^{2-})\), where sulfur has an oxidation state of +6. Permanganate Ion (MnO\(_4^-\)): Reduction: The manganese in MnO\(_4^-\) has an oxidation state of +7. Products: MnO\(_4^-\) is typically reduced to Mn\(^{2+}\) in acidic solutions. Step 2: Write Half-Reactions Oxidation Half-Reaction (SO\(_2\) to SO\(_4^{2-}\)): \(5SO_2 + 5H_2O \longrightarrow 5SO_4^{2-} + 10H^+ + 10e^- \) Reduction Half-Reaction (MnO\(_4^-\) to Mn\(^{2+}\)): \(2MnO_4^- + 16H^+ + 10e^- \longrightarrow 2Mn^{2+} + 8H_2O \) Step 3: Combine the Half-Reactions Balance the number of electrons to combine the half-reactions: Oxidation: \(10e^-\) released Reduction: \(10e^-\) consumed \(5SO_2 + 2MnO_4^- + 2H_2O \longrightarrow 5SO_4^{2-} + 4H^+ + 2Mn^{2+}\) Step 4: Verify the Products and Charges Sulfur: \(5 \times SO_2\) oxidized to \(5 \times SO_4^{2-}\). Manganese: \(2 \times MnO_4^-\) reduced to \(2 \times Mn^{2+}\). Water and Hydrogen Ions: \(H_2O\) is used in the reaction and produces \(H^+\). Conclusion: The overall reaction will be as: \(2H_2O + 5SO_2 + 2MnO_4^- \longrightarrow 5SO_4^{2-} + 4H^+ + 2Mn^{2+}\) |