Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: P Block Elements

Question:

In each of the following question, a statement of Assertion (A) is given followed by a corresponding statement of Reason (R). Choose the correct answer as:

Assertion (A): Ozone is a powerful oxidizing agent in comparison to O2.

Reason (R):  Ozone is diamagnetic but O2 is paramagnetic .

Options:

If both assertion and reason are true, and reason is the correct explanation of the assertion.

If both assertion and reason are true, but the reason is not the correct explanation of the assertion.

If the assertion is true, but the reason is false

If both assertion and reason are false.

Correct Answer:

If both assertion and reason are true, but the reason is not the correct explanation of the assertion.

Explanation:

The correct answer is option 2. If both assertion and reason are true, but the reason is not the correct explanation of the assertion.

Ozone is a powerful oxidizing agent because it decomposes readily under normal conditions and forms nascent oxygen which is a very reactive radical and is responsible for oxidation of a number of substances.

O2 is paramagnetic due to the presence of two unpaired electrons, while O3 is diamagnetic.

The molecular orbital electronic configuration of O2 is :

σ1s2 σ*1s2 σ2s2 σ*2s2 σ2pz2 \(\pi2p_x\)2 \(\pi2p_y\)2 \(\pi \)*2px1\(\pi \)*2py1

However, while both statements are true, the reason provided (R) does not directly explain why ozone is a more powerful oxidizing agent than \(O_2\). The oxidizing power of ozone primarily arises from its ability to readily donate oxygen atoms, not solely from its diamagnetic nature.

Therefore, option 2 is correct: If both assertion and reason are true, but the reason is not the correct explanation of the assertion.