Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Haloalkanes and Haloarenes

Question:

Statement I: Reaction of NH3 with dimethyl either fails to give methyl amine

Statement II: −OCH3 is a good leaving group

Options:

Both statement I and statement II are correct and statement II is the correct explanation of statement I

Both statement I and statement II are correct but statement II is not the correct explanation of statement I

Statement I is correct but statement II is false

Statement I is false but statement II is correct

Correct Answer:

Statement I is correct but statement II is false

Explanation:

The answer is 3. Statement I is correct but statement II is false.

Statement I is correct because the reaction of NH3 with dimethyl ether does not give methyl amine. This is because the −OCH3 group is a poor leaving group. A poor leaving group is a group that is difficult to remove from a molecule. In the case of dimethyl ether, the −OCH3 group is attached to a carbon atom by a single bond. This bond is relatively weak, and it is difficult for the −OCH3 group to break away from the carbon atom.

Statement II is false because −OCH3 is not a good leaving group. A good leaving group is a group that is easily removed from a molecule. In the case of dimethyl ether, the −OCH3 group is not easily removed because it is attached to a carbon atom by a single bond.

Therefore, statement I is correct but statement II is false. The correct explanation for why the reaction of NH3 with dimethyl ether does not give methyl amine is that the −OCH3 group is a poor leaving group.