Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: D and F Block Elements

Question:

The f-block elements are those in which the differentiating electrons enters the (n-2)f orbitals. There are two series of f-Block elements corresponding to filling of 4f and 5f-orbitals. The series of 4f-orbitals is called lanthanides. Lanthanides show different oxidation states depending upon stability of f0, f7 and f14 configurations, though the most common oxidation states is +3. There is a regular decrease in the size of lanthanides ions with increase in atomic number which is known as lanthanides contraction.

The atomic number of three lanthanides elements X, Y and Z are 65, 68 and 70 respectively. What is their Ln3+ electronic configuration?



Options:

 4f8, 4f11, 4f13

 4f11, 4f8, 4f13

 4f0, 4f2, 4f11


 4f3, 4f7, 4f9

Correct Answer:

 4f8, 4f11, 4f13

Explanation:

65Tb : [Xe]4f96s2

Tb3+ :[Xe]4f8

68Er : [Xe]4f126s2

Er3+ : [Xe]4f11

70Yb : [Xe]4f146s2

Yb3+ : [Xe]4f13