Practicing Success
The f-block elements are those in which the differentiating electrons enters the (n-2)f orbitals. There are two series of f-Block elements corresponding to filling of 4f and 5f-orbitals. The series of 4f-orbitals is called lanthanides. Lanthanides show different oxidation states depending upon stability of f0, f7 and f14 configurations, though the most common oxidation states is +3. There is a regular decrease in the size of lanthanides ions with increase in atomic number which is known as lanthanides contraction. |
The atomic number of three lanthanides elements X, Y and Z are 65, 68 and 70 respectively. What is their Ln3+ electronic configuration? |
4f8, 4f11, 4f13 4f11, 4f8, 4f13 4f0, 4f2, 4f11
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4f8, 4f11, 4f13 |
65Tb : [Xe]4f96s2 Tb3+ :[Xe]4f8 68Er : [Xe]4f126s2 Er3+ : [Xe]4f11 70Yb : [Xe]4f146s2 Yb3+ : [Xe]4f13 |