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Salicylaldehyde is formed as a main product from phenol by : |
Kolbe's reaction Reimer Tiemann reaction Kolbe's electrolytic reaction Friedel Craft's reaction |
Reimer Tiemann reaction |
The correct answer is option 2. Reimer Tiemann reaction. Salicylaldehyde can be prepared from phenol using Reimer-Tiemann Reaction. So let us look into the reaction in detail: Reimer Tiemann reaction is a type of substitution reaction named after chemists Karl Reimer and Ferdinand Tiemann. The reaction is used for the ortho-formylation of \(C_6H_5OH\) (phenols). When phenol is treated with chloroform in the presence of sodium hydroxide, an aldehyde group \((-CHO)\) is introduced at the ortho position of the benzene ring leading to the formation of o-hydroxybenzaldehyde. Since hydroxides are not readily soluble in chloroform, a biphasic solvent system is employed to carry out the reaction. This biphasic solvent system can consist of an aqueous hydroxide solution with an organic phase that contains chloroform. Mechanism: It involves electrophilic substitution of the aromatic nucleus, the electrophile being dichloro carbene \((:CCl_2)\) (carbon has only sextet of electrons), formed by the action of strong alkali on chloroform. |