Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Chemical Kinetics

Question:

Statement I: Order of a reaction cannot be written from the balanced equation

Statement II: Rate law can provide some clue about the reaction mechanism

Options:

Statement I and statement II are correct and statement II is correct explanation of statement I

Statement I and statement II are correct but statement II is not the correct explanation of statement I

Statement I is true but statement II is false

Statement I is false but statement II is correct

Correct Answer:

Statement I and statement II are correct but statement II is not the correct explanation of statement I

Explanation:

The correct answer is option 2. Statement I and statement II are correct but statement II is not the correct explanation of statement I.

Let us analyze each of the given statements:

Statement I: Order of a reaction cannot be written from the balanced equation.

This statement is generally true. The order of a reaction, which represents the exponent of the concentration term in the rate equation, cannot be determined solely from the balanced chemical equation. The balanced equation provides information about the stoichiometry of the reaction, indicating the relative ratios of reactants and products involved in the reaction. However, it does not provide information about how the rate of the reaction depends on the concentrations of the reactants. Determining the order of a reaction typically requires experimental data, such as measuring how the rate of the reaction changes with varying concentrations of reactants.

Statement II: Rate law can provide some clue about the reaction mechanism.

This statement is true. The rate law, which is an expression that relates the rate of a chemical reaction to the concentrations of the reactants, can provide insights into the reaction mechanism. By studying the dependence of the reaction rate on the concentrations of the reactants, scientists can infer information about the steps involved in the reaction and the mechanism by which the reaction proceeds. However, the rate law alone may not provide a complete understanding of the reaction mechanism, especially for complex reactions. Additional experimental techniques, such as kinetic studies and computational modeling, may be required to elucidate the detailed reaction mechanism.

Now, let us assess the options: Option: Statement I and Statement II are correct, but Statement II is not the correct explanation of Statement I.

This option is correct. Both statements are true, but Statement II does not directly explain why Statement I is true. While the rate law can provide insights into the reaction mechanism, it does not directly address the inability to determine the order of a reaction from the balanced equation. The determination of the reaction order typically relies on experimental data rather than theoretical considerations based on the rate law. Therefore, Statement I and Statement II are both correct, but Statement II is not the correct explanation of Statement I.