Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Aldehydes, Ketones and Carboxylic Acids

Question:

The reagent involved in the Clemmensen reduction of carbonyl compound is

Options:

Sodium amalgam and HCl

Zinc amalgam and HCl

KOH and ethylene glycol

Zinc amalgam and $HNO_3$

Correct Answer:

Zinc amalgam and HCl

Explanation:

The correct answer is Option (2) → Zinc amalgam and HCl

Clemmensen Reduction:

  • Used to convert carbonyl compounds (aldehydes/ketones) → alkanes
  • Reagent: Zn(Hg) / conc. HCl (zinc amalgam in hydrochloric acid)

Quick comparison of options:

  1. Sodium amalgam and HCl → Used in Birch reduction (not Clemmensen)
  2. Zinc amalgam and HClClemmensen reduction → Correct
  3. KOH and ethylene glycolWolff-Kishner reduction (alternative to Clemmensen)
  4. Zinc amalgam and HNO₃ → Not used (HNO₃ is oxidizing, not reducing)