Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: P Block Elements

Question:

Answer the question on the basis of passage given below:

Nitrogen forms a large number of oxoacids such as $H_2N_2O_2$, (hyponitrous acid), $HNO_2$, (nitrous acid) and $HNO_3$, (nitric acid). Amongst these, $HNO_3$, is the most important. It is used in the manufacture of ammonium nitrate for fertilisers and other nitrates for use in explosives. It is also used to prepare many important organo-nitro compounds like nitroglycerine, trinitrotoluene etc. It acts as a strong oxidizing agent and used as an oxidiser in rocket fuels.

Nitrogen gas is inert at room temperature because

Options:

Nitrogen has lone pair of electrons on it.

Nitrogen atom has very small size.

Nitrogen atoms form a triple bond in nitrogen gas which has a very high bond enthalpy.

Nitrogen atom does not contain any d orbital in its outermost shell.

Correct Answer:

Nitrogen atoms form a triple bond in nitrogen gas which has a very high bond enthalpy.

Explanation:

The correct answer is Option (3) → Nitrogen atoms form a triple bond in nitrogen gas which has a very high bond enthalpy.

The correct explanation for why nitrogen gas (N₂) is inert at room temperature is : Nitrogen atoms form a triple bond in nitrogen gas which has a very high bond enthalpy

Triple Bond Formation: Nitrogen gas consists of two nitrogen atoms bonded together by a triple bond (N≡N). This triple bond involves one sigma bond and two pi bonds.

High Bond Enthalpy: The bond enthalpy (or bond dissociation energy) of the N≡N triple bond is very high (about 945 kJ/mol). This means that a significant amount of energy is required to break this bond, making N₂ relatively stable and unreactive under normal conditions

Inert Nature: Because of the strength of the triple bond, nitrogen gas does not readily react with other substances at room temperature, which is why it is considered inert.

Incorrect Options:

Lone Pair of Electrons: While nitrogen does have lone pairs, this does not directly explain its inertness; instead, it affects reactivity in other contexts.

Small Size: The small size of the nitrogen atom contributes to its ability to form strong bonds, but it's not the primary reason for its inertness.

Lack of d Orbitals: Nitrogen's lack of d orbitals does not play a significant role in its reactivity or inertness.

In summary, the high bond enthalpy of the triple bond in N₂ is the main reason for its inertness at room temperature.