Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Alcohols, Phenols and Ethers

Question:

Both alcohols and phenols contain a hydroxyl group, but phenols are more acidic than alcohols. Whereas the acid strength of aliphatic alcohols mainly depends upon the inductive effects, and acid strength of phenols depends upon a combination of both inductive and resonance effects of the substituent and its position on the benzene ring.

Identify the strongest acid.

Options:

o-Methoxyphenol

p-Methoxyphenol

m-Methoxyphenol

Phenol

Correct Answer:

m-Methoxyphenol

Explanation:
m-Methoxy phenol is the strongest acid. 
Methoxy group at meta position exerts an only-I effect.
Due to this, it withdraws electrons from all the nuclear position of the benzene ring including the one holding the OH group consequently, electron density in the OH bond decreases. 
Hence, m-methoxy phenol becomes more acidic than o and p-methoxy phenols.