Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Chemical Kinetics

Question:

For an endothermic reaction, where ΔH represents the enthalpy of reaction in KJ/mol. The higher value for the energy of activation will be equal to which of the following? 

Options:

Less than ΔH

Zero

More than ΔH

Equal to ΔH

Correct Answer:

More than ΔH

Explanation:

Activation energy: Ea is the energy that must be possessed by the molecules in excess to the average energy at a given temperature to enter a chemical reaction.

Relation between activation energy and enthalpy of a reversible reaction:
If the reaction is endothermic in forward direction, then Ea(backward)​ Ea(forward)​ ΔH
If the reaction is exothermic in forward direction, then Ea(backward)​ Ea(forwardΔH
For an endothermic reaction, where ΔH represents the enthalpy of 
the reaction in kJmol1, the minimum value for the energy of activation will be slightly more than ΔH.