Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Aldehydes, Ketones and Carboxylic Acids

Question:

Give IUPAC name of the following compound:

$CH_3-CH_2-CH_2-CH(Br)-CH(CH_3)-CH_2-CHO$

Options:

3-Bromo-2-methylhexanal

4-Bromo-3-methylheptanol

4-Bromo-5-methylheptanal

4-Bromo-3-methylheptanal

Correct Answer:

4-Bromo-3-methylheptanal

Explanation:

The correct answer is Option (4) → 4-Bromo-3-methylheptanal

To determine the IUPAC name, follow the systematic steps of nomenclature.

Step 1: Identify the principal functional group

The compound contains the –CHO group, which represents an aldehyde.

Aldehydes take priority in numbering and naming.

Thus, the parent suffix will be:

–al

Step 2: Identify the longest carbon chain containing –CHO

Counting from the aldehyde carbon:

CHO – CHâ‚‚ – CH(CH₃) – CH(Br) – CHâ‚‚ – CHâ‚‚ – CH₃

Total carbon atoms = 7

Therefore the parent chain is:

heptanal

Step 3: Number the chain

Numbering starts from the aldehyde carbon (C-1).

1 – CHO

2 – CHâ‚‚

3 – CH(CH₃)

4 – CH(Br)

5 – CHâ‚‚

6 – CHâ‚‚

7 – CH₃

Step 4: Identify substituents

Substituents present:

  • Methyl group at C-3
  • Bromo group at C-4

Step 5: Arrange substituents alphabetically

Substituents are written in alphabetical order:

Bromo before Methyl

Thus the name becomes:

4-Bromo-3-methylheptanal