Give IUPAC name of the following compound: $CH_3-CH_2-CH_2-CH(Br)-CH(CH_3)-CH_2-CHO$ |
3-Bromo-2-methylhexanal 4-Bromo-3-methylheptanol 4-Bromo-5-methylheptanal 4-Bromo-3-methylheptanal |
4-Bromo-3-methylheptanal |
The correct answer is Option (4) → 4-Bromo-3-methylheptanal To determine the IUPAC name, follow the systematic steps of nomenclature. Step 1: Identify the principal functional group The compound contains the –CHO group, which represents an aldehyde. Aldehydes take priority in numbering and naming. Thus, the parent suffix will be: –al Step 2: Identify the longest carbon chain containing –CHO Counting from the aldehyde carbon: CHO – CHâ‚‚ – CH(CH₃) – CH(Br) – CHâ‚‚ – CHâ‚‚ – CH₃ Total carbon atoms = 7 Therefore the parent chain is: heptanal Step 3: Number the chain Numbering starts from the aldehyde carbon (C-1). 1 – CHO 2 – CHâ‚‚ 3 – CH(CH₃) 4 – CH(Br) 5 – CHâ‚‚ 6 – CHâ‚‚ 7 – CH₃ Step 4: Identify substituents Substituents present:
Step 5: Arrange substituents alphabetically Substituents are written in alphabetical order: Bromo before Methyl Thus the name becomes: 4-Bromo-3-methylheptanal |