Read the passage carefully and answer the Questions. Haloalkanes undergo nucelophilic substitution reactions owing to the polarity of C-X bond. The nucleophile reacts with the haloalkane on the carbon possessing a partial positive charge holding the halogen atom. The halogen atom X is replaced by a nucleophile. Depending on the kinetics and mode of bond breaking, the mechanism can be either $S_N1$ or $S_N2$ reaction. The rate of $S_N1$ reaction is governed by the stability of carbocation and in $S_N2$ reaction, the rate of reaction is governed by steric factor. Chirality is the main factor in both $S_N1$ and $S_N2$. In $S_N1$ reaction, the chirality of alkyl halide is accompanied by racemization of the product, while in $S_N2$ reaction, the product is characterized by inversion of configuration. The structure of alkyl halide and the nature of the solvent also governs the mechanism of the substitution. |
Hydrolysis of 2-Chlorobutane will result in formation of |
(+) 2-Butanol (-) 2-butanol (±) 2-Butanol 2-Butanol |
2-Butanol |
The correct answer is Option (4) → 2-Butanol ** Hydrolysis of 2-chlorobutane occurs through the SN1 mechanism because it forms a secondary carbocation. SN1 reactions lead to racemization (mix of both enantiomers), since the nucleophile can attack from either side. Therefore, the product will be a racemic mixture: ✅ (±) 2-Butanol |