The major product of the following reaction is
Answer & explanation
Correct answer: option 4
The correct answer is Option (4) →
Core Concept - Friedel-Crafts Alkylation
This is an electrophilic aromatic substitution.
$OCH_3$ group is:
- Strongly activating
- Ortho/para directing due to +M (resonance donation)
Electophile formed: $CH_3^+$
So substitution occurs at ortho and para positions relative to $-\text{OCH}_3$.
Now check steric effect
|
Position |
Electronic Effect |
Steric Effect |
Result |
|
Ortho |
Favored |
Crowded near $-\text{OCH}_3$ |
Minor product |
|
Para |
Favored |
Less steric hindrance |
Major product |
|
Meta |
Not activated |
--- |
Not formed |
Anisole undergoes Friedel-Crafts reaction, i.e., the alkyl and acyl groups are introduced at ortho and para positions by reaction with alkyl halide and acyl halide in the presence of anhydrous aluminium chloride (a Lewis acid) as catalyst.