Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Chemical Kinetics

Question:

50 % of a first order reaction completes in 20 minutes. What will be the time taken for 100% completion of the same reaction?

Options:

5 minutes

40 minutes

20 minutes

Infinite time

Correct Answer:

Infinite time

Explanation:

For first order reaction,

t1/2 = \(\frac{0.693}{k}\) 

20 = \(\frac{0.693}{k}\) 

k = \(\frac{0.693}{20}\) = 0.03465 s-1 

t = \(\frac{2.303}{k}\)log\(\frac{a}{a-x}\)

t100% = \(\frac{2.303}{0.03465}\)log\(\frac{100}{0}\)

t100% = \(\frac{2.303}{0.03465}\)log∞

t100% = ∞ (infinite time)