Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Amines

Question:

Match List-I with List-II

List-I

List-II

(A) Gatterman's reaction

(I) Alkyl isocyanide

(B) Carbylamine reaction

(II) Azo Compound

(C) Hoffmann bromamide reaction

(III) Aryl Halide

(D). Coupling reaction

(IV) Primary amine

Choose the correct answer from the options given below:

Options:

(A)-(III), (B)-(I), (C)-(IV), (D)-(II)

(A)-(III), (B)-(I), (C)-(II), (D)-(IV)

(A)-(I), (B)-(II), (C)-(IV), (D)-(III)

(A)-(III), (B)-(IV), (C)-(I), (D)-(II)

Correct Answer:

(A)-(III), (B)-(I), (C)-(IV), (D)-(II)

Explanation:

The correct answer is Option (1) → (A)-(III), (B)-(I), (C)-(IV), (D)-(II)

List-I

List-II

(A) Gatterman's reaction

(III) Aryl Halide

(B) Carbylamine reaction

(I) Alkyl isocyanide

(C) Hoffmann bromamide reaction

(IV) Primary amine

(D) Coupling reaction

(II) Azo Compound

 

(A) Gattermann Reaction → (III) Aryl Halide
In Gattermann reaction, a diazonium salt is converted into aryl chloride or aryl bromide using HCl/HBr and copper powder. Hence product is aryl halide.

(B) Carbylamine Reaction → (I) Alkyl Isocyanide
Primary amines when heated with chloroform and alcoholic KOH give isocyanides (foul smell). Hence alkyl isocyanide.

(C) Hoffmann Bromamide Reaction → (IV) Primary Amine
Amide reacts with bromine and KOH to form a primary amine with one carbon less.

(D) Coupling Reaction → (II) Azo Compound
Diazonium salts react with phenols or amines to form azo dyes (–N=N– linkage).