Converge

The most appropriate antonym of the word converge is disperse.

• Converge means to come together from different directions or points.
• Disperse means to spread out or scatter in different directions.

The other words do not have the same meaning as converge and are therefore not antonyms.

• Congregate means to gather together in a group.
• Gather means to collect or bring together.
• Convene means to assemble or meet together.