Practicing Success
Case: Read the passage and answer the following questions Crystal field theory (CFT) describes the breaking of degeneracies of electron orbital states, usually d or f orbitals, due to a static electric field produced by a surrounding charge distribution (anion neighbours). This theory has been used to describe various spectroscopies of transition metal coordination complexes, in particular optical spectra (colours). CFT successfully accounts for some magnetic properties, colours, hydration enthalpies, and spinel structures of transition metal complexes, but it does not attempt to describe bonding. |
What will be the crystal field splitting energy for a high spin d4 octahedral complex? |
0.6 Δo -0.6 Δo 0.8 Δo -0.8 Δo |
-0.6 Δo |
For a high spin d4 configuration, electrons are distributed as t2g3 eg2 So CFSE = 3 x (-0.4) + 0.6 = -1.2+0.6 = -0.6 |