Practicing Success
Match Column I with Column II
|
A-r, B-p, C-s, D-q A-p, B-r, C-q, D_s A-q, B-r, C-p, D-s A-s, B-r, C-q, D-p |
A-r, B-p, C-s, D-q |
The correct answer is option 1. A-r, B-p, C-s, D-q A. The given complex is \(K[Cr(H_2O)_2(C_2O_4)_2].3H_20\) Let the oxidation number of \(Cr\) be \(x\) \(∴ 1 + x + 2 × 0 + 2(−2) = 0\) \(⇒ x = 3\) So, the electronic configuration of Cr in +3 oxidation state is \(Cr^{3+} = _{18}Ar] 4s^0 3d^3\) Here, the number of unpaired electrons, \(n = 3\) Therefore, the magnetic moment is \(\mu = \sqrt{3(3 + 2)} = 3.87 BM\) i.e., (r) B. The given complex is \(K_4[Mn(CN)_6]\) Let the oxidation number of \(Mn\) be \(x\) \(∴ 4 + x + 6 × (−1) = 0\) \(⇒ x = 2\) So, the electronic configuration of Mn in +2 oxidation state is \(Mn^{2+} = _{18}Ar] 4s^0 3d^5\) But due to the presence of a strong field ligand pairing of the electrons occurs and so the d-orbital can be presented as Here, the number of unpaired electrons, \(n = 1\) Therefore, the magnetic moment is \(\mu = \sqrt{1(1 + 2)} = 1.73 BM\) i.e., (p) C. The given complex is \([Co(NH_3)_5Cl]Cl_2\) Let the oxidation number of \(Co\) be \(x\) \(∴ x + 3 × 0 + (−1) + (−2)= 0\) \(⇒ x = 3\) So, the electronic configuration of Co in +3 oxidation state is \(Co^{3+} = _{18}Ar] 4s^0 3d^6\) But due to the presence of the strong field ligand pairing of electrons occurs in the d-orbital in the \(t_{2g}\) level So, the number of unpaired electrons, \(n = 0\) [ due to pairing] Therefore, the magnetic moment is \(\mu = \sqrt{0(0 + 2)} = 0 BM\) i.e., (s) D. The given complex is \(Cs[FeCl_4]\) Let the oxidation number of \(Fe\) be \(x\) \(∴ 1 + x + 4 × (−1) = 0\) \(⇒ x = 3\) So, the electronic configuration of Fe in +3 oxidation state is \(Fe^{3+} = _{18}Ar] 4s^0 3d^5\) Here, the number of unpaired electrons, \(n = 5\) Therefore, the magnetic moment is \(\mu = \sqrt{5(5 + 2)} = 5.92 BM\) i.e., (q) The correct answer is (a) A-r, B-p, C-s, D-q |