Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Alcohols, Phenols and Ethers

Question:

What is the main product in the reaction between benzene (C6H6) and oleum followed by reaction with sodium hydroxide (NaOH) and a proton (H+)?

Options:

Benzene sulphonic acid 

Phenol

cresol

catechol

Correct Answer:

Phenol

Explanation:

Benzene is sulphonated with oleum and benzene sulphonic acid so formed is converted to sodium phenoxide on heating with molten sodium hydroxide. Acidification of the sodium salt gives phenol.

C6H+ oleum ---> C6H5-SO3H + NaOH/H+   -----> C6H5OH