In the atomic hydrogen line spectrum, the wavelength of the first line of the Lyman series is (Given: Rydberg constant $R = 1.097×10^7\, m^{-1}$) |
91 nm 122 nm 365 nm 656 nm |
122 nm |
The correct answer is Option (2) → 122 nm For the Lyman series, the electronic transition ends at $n_1 = 1$. The first line corresponds to the transition from $n_2 = 2$ to $n_1 = 1$. The wavelength is given by the Rydberg formula: $\frac{1}{\lambda} = R \left( \frac{1}{n_1^2} - \frac{1}{n_2^2} \right)$ Substitute values: $\frac{1}{\lambda} = 1.097 \times 10^7 \left( \frac{1}{1^2} - \frac{1}{2^2} \right)$ $\frac{1}{\lambda} = 1.097 \times 10^7 \left( 1 - \frac{1}{4} \right) = 1.097 \times 10^7 \times \frac{3}{4}$ $\frac{1}{\lambda} = 8.2275 \times 10^6$ $\lambda = \frac{1}{8.2275 \times 10^6} \approx 1.215 \times 10^{-7} \ \text{m} = 121.5 \ \text{nm}$ |