One mole of an ideal gas is allowed to expand reversibly and adiabatically from a temperature of \(27°C\). If the work done during the process is \(3\, \ kJ\), the final temperature will be equal to \((C_v = 20 JK^{–1})\) |
150K 100 K 26.85 K 295 K |
150K |
The correct answer is option 1. 150 K. We know, from the First law of Thermodynamics, \(\Delta U = q + W\, \ ------(1)\) We know, for adiabatic condition, \(q = 0\) Thus, equation \((1)\) becomes \(\Delta U = W\, \ -----(2)\) At constant volume \(\Delta U = nC_v\Delta T\, \ -----(3)\) From equation \((1)\) and \((3)\) wehave \(W = nC_v\Delta T\, \ -------(4)\) Given, \(T_i = 27^oC = 27 + 273 = 300\, \ K\) \(T_f = T\, \ (say)\) Thus, \(\Delta T = T_i - T_f\) or, \(\Delta T = 300 - T\) \(C_v = 20 JK^{–1}\) \(W = -3\, \ kJ = -3 \times 10^3\) (∵ Work done by the gas is negative) Substituting these values in equation \((4)\), we get \(- 3000 = 1 \times 20 \times (T - 300)\) \(⇒ T - 300 = -150\) \(⇒ T = 300 - 150\) \(⇒ T = 150\, \ K\) |