Practicing Success
Molar conductance at infinite dilution of Mg(NO3)2, H2SO4 and HNO3 solution in water are x, y and z respectively. What is the Molar conductance of MgSO4 solution? |
x - y + z x + 2y + z x + y - 2z x - y + 2z |
x + y - 2z |
Mg(NO3)2 ⇔ Mg2+ + 2NO3- ΛMg(NO3)2 = ΛMg2+ + 2ΛNO3- x = ΛMg2+ + 2ΛNO3- .......(i) H2SO4 ⇔ 2H+ + SO42- ΛH2SO4 = 2ΛH+ + ΛSO42- y = 2ΛH+ + ΛSO42- .......(ii) HNO3 ⇔ H+ + NO3- ΛHNO3 = ΛH+ + ΛNO3- z = ΛH+ + ΛNO3- .......(iii) On Applying (i) + (ii) - 2(iii), we get ΛMgSO4 = x + y - 2z |