The solutions that show large negative deviation from Raoult’s law forms which type of azeotropes?

Maximum boiling azeotrope

The solutions that show large negative deviation from Raoult’s law form maximum boiling azeotrope at a specific composition. Mixture of Nitric acid and water is an example of this class of azeotrope. This azeotrope has the approximate composition, 68% nitric acid and 32% water by mass, with a boiling point of 393.5 K.