Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Solutions

Question:

18 g of a non-volatile solute A is dissolved in 1 kg of water, the boiling point of water is raised to 373.51 K. Given Kb for water is 0.52 K kg mol-1, Boiling point of water is 373.15 K at 1.013 bar pressure. The molecular weight of the solid A is

Options:

58.0 g mol-1

26.0 g mol-1

55.0 g mol-1

110.0 g mol-1

Correct Answer:

26.0 g mol-1

Explanation:

Elevation in boiling point, ΔTb = 373.51 - 373.15 = 0.36 K

ΔTb = kb m

0.36 = 0.52 x \(\frac{\frac{18}{x}}{1}\)

x = \(\frac{18 × 0.52}{0.36}\) 

x = 26 g mol-1