Which of the following option is correct by using Coulomb's law.
Answer & explanation
Correct answer: option 4
The correct answer is Option (4)

(if the product of \( q_1q_2 \) is negative)
By Coulomb's law the forces between two point charges act along the line joining them, and the force on \( q_1 \) due to \( q_2 \) is equal and opposite to the force on \( q_2 \) due to \( q_1 \).
\( \displaystyle \vec{F}_{12} = -\vec{F}_{21} \)
If \( q_1q_2 \gt 0 \) (like charges) the forces are repulsive: each force points away from the other charge. If \( q_1q_2 \lt 0 \) (unlike charges) they are attractive: each force points towards the other charge.
In Option (4) the product is negative, \( \vec{F}_{12} \) on \( q_1 \) points towards \( q_2 \), and \( \vec{F}_{21} \) on \( q_2 \) points towards \( q_1 \). The two forces lie along the line joining the charges and are equal and opposite, which is the correct picture of attraction.
Why the other options are incorrect

(if the product of \( q_1q_2 \) is positive)
Option (1) — Incorrect. For a positive product the force on \( q_1 \) correctly points away from \( q_2 \), but \( \vec{F}_{21} \) is drawn at an angle to the line joining the charges. Coulomb forces act only along that line.

(if the product of \( q_1q_2 \) is negative)
Option (2) — Incorrect. For a negative product both forces should point towards the other charge. Here \( \vec{F}_{21} \) points away from \( q_1 \), and the two forces point the same way instead of being opposite.

(if the product of \( q_1q_2 \) is positive)
Option (3) — Incorrect. For a positive product both forces should point away from each other. Here \( \vec{F}_{21} \) points towards \( q_1 \), and the two forces point the same way instead of being opposite.
NCERT (2026-27):
Coulomb’s Law – “… Equation (1.3) is valid for any sign of q1 and q2 whether positive or negative. If q1 and q2 are of the same sign (either both positive or both negative), \( \mathbf{F}_{21} \) is along \( \hat{\mathbf{r}}_{21} \), which denotes repulsion, as it should be for like charges. If q1 and q2 are of opposite signs, \( \mathbf{F}_{21} \) is along \( -\hat{\mathbf{r}}_{21} \) (\( = \hat{\mathbf{r}}_{12} \)), which denotes attraction, as expected for unlike charges.”
Coulomb’s Law – “… The force \( \mathbf{F}_{12} \) on charge q1 due to charge q2, is obtained from Eq. (1.3), by simply interchanging 1 and 2, i.e.,
\( \displaystyle \mathbf{F}_{12} = -\mathbf{F}_{21} \)
Thus, Coulomb’s law agrees with the Newton’s third law.”