Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: Coordination Compounds

Question:

What is the IUPAC name of [Co(NH3)6]SO4?

Options:

Hexaaminecobalt(II)sulphate

Hexaamminecobalt(II)sulphate

Hexaamminecobalt(II)sulphato

Hexaamminecobalt(IV)sulphate

Correct Answer:

Hexaamminecobalt(II)sulphate

Explanation:

The IUPAC name of the complex \([Co(NH_3)_6]SO_4\) is hexaamminecobalt(II) sulphate.

Here's how the name is derived:

  1. Start with the central metal ion: cobalt (Co).
  2. Indicate the coordination number in Roman numerals: (II) indicates that cobalt has a +2 oxidation state.
  3. Specify the ligands: The ligands in this complex are ammonia (NH3), and there are six ammonia ligands present. Each ammonia ligand is called "ammine."
  4. Write the ligands in alphabetical order followed by their multiplicity (in this case, "hexa" indicates six): hexaammine.
  5. Finally, indicate the counterion, which is sulphate (SO4). Since sulphate is a common anion, its name remains unchanged.

Putting it all together, the IUPAC name of \([Co(NH_3)_6]SO_4\) is hexaamminecobalt(II) sulphate.