The IUPAC name of the complex \([Pt(NH_3)_2Cl(NH_2CH_3)]Cl\) is: |
Diaminechloromethylamineplatinum(II) chloride Diaminechloridomethylamineplatinum (III) chloride Diamminechloridomethylamineplatinum(II) chloride Diamminechloridomethaneamineplatinum(II) chloride |
Diamminechloridomethylamineplatinum(II) chloride |
The correct answer is option 3. Diamminechloridomethylamineplatinum(II) chloride. The complex \([Pt(NH_3)_2Cl(NH_2CH_3)]Cl\) consists of: \(Pt\) (platinum) as the central metal ion. \(NH_3\) (ammonia) as a neutral ligand. \(Cl\) (chloride) as a ligand. \(NH_2CH_3\) (methylamine) as another neutral ligand. \(Cl\) (chloride) outside the coordination sphere. Step-by-step IUPAC Naming: Naming the ligands: The ligand \(NH_3\) (ammonia) is named ammine. The ligand \(Cl\) (chloride attached to platinum) is named chlorido. The ligand \(NH_2CH_3\) (methylamine) is named methylamine. Order of ligands: In IUPAC nomenclature, ligands are named in alphabetical order, so "ammine" comes before "chlorido" and "methylamine." Oxidation state of platinum: The overall charge of the complex ion is neutral because the coordination sphere is \([Pt(NH_3)_2Cl(NH_2CH_3)]^+\) and there is one chloride ion \((Cl^-)\) outside the coordination sphere. Platinum is in the +2 oxidation state, which is denoted as (II). Chloride outside the complex: The chloride ion outside the coordination sphere is written as "chloride" at the end. The IUPAC name of the complex \([Pt(NH_3)_2Cl(NH_2CH_3)]Cl\) is Diamminechloridomethylamineplatinum(II) chloride. |