Practicing Success
Liquid A and B form an ideal solution at 30oC. At this temperature vapour pressure of pure A and pure B is 200 mm Hg and 50 mm Hg respectively. Calculate the vapour pressure of the solution at same temperature if 3 moles of A and 1 mole of B are added. (Given: Molecular mass of A and B are 40 and 60 respectively) |
162.5 mm Hg 152.5 mm Hg 142.5 mm Hg None of these |
162.5 mm Hg |
XA = \(\frac{n_A}{n_A + n_B}\) = \(\frac{3}{3+1}\) = \(\frac{3}{4}\) XB = \(\frac{1}{4}\) PT = PA + PB = PoAXA + PoBXB = 200 x \(\frac{3}{4}\) + 50 x \(\frac{1}{4}\) = 162.5 mm Hg |