Arrange the following series of emission lines in the spectrum of hydrogen atom in sequence according to their increasing wavelengths
(A) Paschen series
(B) Lyman series
(C) Balmer series
Choose the correct answer from the options given below:
Answer & explanation
Correct answer: option 2
The correct answer is Option (2) → (B), (C), (A)
Each series of the hydrogen spectrum is named by the lower level \( n_1 \) in which the electron lands: \( n_1 = 1 \) for Lyman, \( n_1 = 2 \) for Balmer and \( n_1 = 3 \) for Paschen. The wavelength follows from
\( \displaystyle \frac{1}{\lambda} = R\left(\frac{1}{n_1^{2}} - \frac{1}{n_2^{2}}\right) \)
The lower the final level, the larger the energy released and the shorter the wavelength. The first (longest-wavelength) line of each series is
\( \displaystyle \text{Lyman: } \frac{1}{\lambda} = \frac{3R}{4} \;\Rightarrow\; \lambda \approx 122\,\mathrm{nm} \)
\( \displaystyle \text{Balmer: } \frac{1}{\lambda} = \frac{5R}{36} \;\Rightarrow\; \lambda \approx 656\,\mathrm{nm} \)
\( \displaystyle \text{Paschen: } \frac{1}{\lambda} = \frac{7R}{144} \;\Rightarrow\; \lambda \approx 1875\,\mathrm{nm} \)
So the order of increasing wavelength is Lyman, Balmer, Paschen, that is (B), (C), (A).
Note: This question is from the pre-rationalised NCERT book (2022-23). The topic was removed from the latest NCERT book (2026-27), but it is still in the CUET 2026 syllabus, so do not skip it.
NCERT (Pre-rationalised edition, 2022-23):
Spectral Series – “… In 1885, the first such series was observed by a Swedish school teacher Johann Jakob Balmer (1825–1898) in the visible region of the hydrogen spectrum. This series is called Balmer series (Fig. 12.6).”
Spectral Series – “… The Lyman series is in the ultraviolet, and the Paschen and Brackett series are in the infrared region.”