Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Solutions

Question:

Van’t Hoff factor for a dilute solution of sodium argento cyanide is:

Options:

2

0.25

3.0

0.50

Correct Answer:

2

Explanation:

The compound is sodium argento cyanide, i.e., \(Na[Ag(CN)_2]\).

The dissociation reaction is,

\(Na[Ag(CN)_2]\) \(Na^+\) + \([Ag(CN)_2]^−\)
\(1\)   0   0
\(1 − \alpha\)   \(\alpha \)   \(\alpha \)

van't Hoff factor, \(i =1 + \alpha\)

For very dilute solution,

\(\alpha = 1\)

Hence \(i = 1 + 1 = 2\)