Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Aldehydes, Ketones and Carboxylic Acids

Question:

Match List-I with List-II

List-I Name Reaction

List-II Reagent

(A) Rosemund Reaction

(I) $CO/HCl$, anhyd. $AlCl_3, CuCl$

(B) Stephen Reaction

(II) $CrO_2Cl_2$

(C) Etard Reaction

(III) $SnCl_2$ and $HCl$

(D) Gatterman Koch Reaction

(IV) $H_2,Pd-BaSO_4$

Choose the correct answer from the options given below:

Options:

(A)-(IV), (B)-(III), (C)-(II), (D)-(I)

(A)-(I), (B)-(II), (C)-(III), (D)-(IV)

(A)-(I), (B)-(II), (C)-(IV), (D)-(III)

(A)-(III), (B)-(IV), (C)-(I), (D)-(II)

Correct Answer:

(A)-(IV), (B)-(III), (C)-(II), (D)-(I)

Explanation:

The correct answer is Option (1) → (A)-(IV), (B)-(III), (C)-(II), (D)-(I)

List-I Name Reaction

List-II Reagent

(A) Rosemund Reaction

(IV) $H_2,Pd-BaSO_4$

(B) Stephen Reaction

(III) $SnCl_2$ and $HCl$

(C) Etard Reaction

(II) $CrO_2Cl_2$

(D) Gatterman Koch Reaction

(I) $CO/HCl$, anhyd. $AlCl_3, CuCl$

  • Rosenmund Reaction: Reduction of acid chloride to aldehyde → H₂, Pd–BaSO₄ (often with sulfur or quinoline as poison).
  • Stephen Reaction: Conversion of alkyl cyanide (R–CN) to aldehyde → SnCl₂ + HCl (then hydrolysis).
  • Etard Reaction: Oxidation of toluene (or alkyl benzene) to benzaldehyde → CrO₂Cl₂ (chromyl chloride).
  • Gattermann-Koch Reaction: Formylation of aromatic ring to give Ar–CHO → CO + HCl, anhyd. AlCl₃, CuCl.