The correct answer is Option (1) → (A)-(IV), (B)-(III), (C)-(II), (D)-(I)
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List-I Name Reaction
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List-II Reagent
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(A) Rosemund Reaction
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(IV) $H_2,Pd-BaSO_4$
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(B) Stephen Reaction
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(III) $SnCl_2$ and $HCl$
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(C) Etard Reaction
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(II) $CrO_2Cl_2$
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(D) Gatterman Koch Reaction
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(I) $CO/HCl$, anhyd. $AlCl_3, CuCl$
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- Rosenmund Reaction: Reduction of acid chloride to aldehyde → H₂, Pd–BaSO₄ (often with sulfur or quinoline as poison).
- Stephen Reaction: Conversion of alkyl cyanide (R–CN) to aldehyde → SnCl₂ + HCl (then hydrolysis).
- Etard Reaction: Oxidation of toluene (or alkyl benzene) to benzaldehyde → CrO₂Cl₂ (chromyl chloride).
- Gattermann-Koch Reaction: Formylation of aromatic ring to give Ar–CHO → CO + HCl, anhyd. AlCl₃, CuCl.
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