Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Biomolecules

Question:

What is the product obtained when glucose is reduced in the presence of sodium amalgam? 

Options:

Gluconic acid

Glucaric acid 

Sorbitol 

Hexane

Correct Answer:

Sorbitol 

Explanation:

The correct answer is option 3. Sorbitol.

When glucose is reduced in the presence of sodium amalgam, the product obtained is Sorbitol.

Reduction of Glucose: When glucose undergoes reduction, the aldehyde group (\(-CHO\)) at the first carbon is reduced to a primary alcohol group (\(-CH_2OH\)).

Sodium Amalgam: This is a reducing agent that provides the necessary electrons for the reduction process.

Process: Glucose is an aldohexose, meaning it has an aldehyde group at carbon 1 and hydroxyl groups on the other carbons.

Reduction Reaction: The aldehyde group (\(-CHO\)) of glucose is reduced to an alcohol group (\(-CH_2OH\)).

Sorbitol Formation: This reaction converts the aldehyde group of glucose to an additional hydroxyl group, resulting in sorbitol (a sugar alcohol).

Summary of Options:

Gluconic Acid: Formed by the oxidation of glucose, not reduction.

Glucaric Acid: Formed by the oxidation of glucose at both the aldehyde group and the primary alcohol group.

Sorbitol: Formed by the reduction of the aldehyde group of glucose to an alcohol group.

Hexane: Not related to the reduction of glucose.

Thus, the correct product obtained when glucose is reduced in the presence of sodium amalgam is: Sorbitol.