The specific conductance of a decinormal KCl solution is \( 0.0121\, ohm^{-1}\, cm^{-1} \) and the resistance was found to be 56 ohm. Cell constant for the reaction will be
Answer & explanation
Correct answer: option 1
The correct answer is Option (1) → \( 0.6776\, cm^{-1} \)
The resistance of a solution in a conductivity cell depends on the distance l between the electrodes and their area A. The ratio \( l/A \) is the cell constant, \( G^{*} \), and it links the measured resistance to the conductivity (specific conductance) \( \kappa \):
\( \displaystyle \kappa = \frac{1}{R} \times \frac{l}{A} = \frac{G^{*}}{R} \)
\( \displaystyle G^{*} = \kappa \times R \)
Substituting \( \kappa = 0.0121\,\mathrm{ohm^{-1}\,cm^{-1}} \) and \( R = 56\,\mathrm{ohm} \):
\( \displaystyle G^{*} = 0.0121\,\mathrm{ohm^{-1}\,cm^{-1}} \times 56\,\mathrm{ohm} = 0.6776\,\mathrm{cm^{-1}} \)
So the cell constant is 0.6776 cm−1. This is how a cell constant is found in practice: a KCl solution of known conductivity is placed in the cell and its resistance is measured.