Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Electro Chemistry

Question:

Mercury cell used in hearing aid devices contains anode comprising of

Options:

Copper-mercury amalgam

Zinc-mercury amalgam

Platinum-mercury amalgam

Carbon-mercury amalgam

Correct Answer:

Zinc-mercury amalgam

Explanation:

The correct answer is Option (2) → Zinc-mercury amalgam

The mercury cell (also known as the mercuric oxide-zinc battery), historically used in hearing aids for its stable 1.35 V output and long shelf life, has an anode made of zinc-mercury amalgam (Zn(Hg)). This amalgam prevents unwanted side reactions like hydrogen gas evolution and zinc corrosion in the alkaline electrolyte.

The cathode is a paste of HgO mixed with carbon or graphite, and the electrolyte is typically KOH (or NaOH) paste, often with ZnO.

Anode reaction: Zn(Hg) + 2OH⁻ → ZnO + H₂O + 2e⁻

Cathode reaction: HgO + H₂O + 2e⁻ → Hg + 2OH⁻