Mercury cell used in hearing aid devices contains anode comprising of |
Copper-mercury amalgam Zinc-mercury amalgam Platinum-mercury amalgam Carbon-mercury amalgam |
Zinc-mercury amalgam |
The correct answer is Option (2) → Zinc-mercury amalgam The mercury cell (also known as the mercuric oxide-zinc battery), historically used in hearing aids for its stable 1.35 V output and long shelf life, has an anode made of zinc-mercury amalgam (Zn(Hg)). This amalgam prevents unwanted side reactions like hydrogen gas evolution and zinc corrosion in the alkaline electrolyte. The cathode is a paste of HgO mixed with carbon or graphite, and the electrolyte is typically KOH (or NaOH) paste, often with ZnO. Anode reaction: Zn(Hg) + 2OH⁻ → ZnO + H₂O + 2e⁻ Cathode reaction: HgO + H₂O + 2e⁻ → Hg + 2OH⁻
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