If \(KMnO_4\) is reduced by oxalic acid in the acidic medium, then the oxidation number of \(Mn\) changes from:
Answer & explanation
Correct answer: option 3
The correct answer is Option (3) → +7 to +2
In acidic medium, permanganate oxidises oxalic acid (oxalate) to \( \ce{CO2} \) and is itself reduced to \( \ce{Mn^{2+}} \):
\( \ce{5C2O4^{2-}} \) + \( \ce{2MnO4^{-}} \) + \( \ce{16H^{+}} \) → \( \ce{2Mn^{2+}} \) + \( \ce{8H2O} \) + \( \ce{10CO2} \)
In \( \ce{MnO4^{-}} \): x + 4(−2) = −1 ⇒ x = +7. In \( \ce{Mn^{2+}} \) the oxidation number is +2. So Mn changes from +7 to +2 (five electrons gained per Mn).
NCERT (2026-27 edition):
Oxides and Oxoanions of Metals – “… (c) Oxalate ion or oxalic acid is oxidised at 333 K:
5C2O42– + 2MnO4– + 16H+ → 2Mn2+ + 8H2O + 10CO2”