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Home/Practice questions/Chemistry
ChemistryPhysical: Chemical Kinetics

The rate constant of a first-order reaction is 10−2 min−1. The half-l…

The rate constant of a first-order reaction is 10−2 min−1. The half-life period of the reaction is:

Answer & explanation+

Correct answer: option 2

The correct answer is Option (2) → 69.3 min

For a first order reaction the half-life depends only on the rate constant, not on the initial concentration:

    \( \displaystyle t_{1/2}=\frac{0.693}{k} \)

Substituting k = 10−2 min−1:

    \( \displaystyle t_{1/2}=\frac{0.693}{10^{-2}\,\mathrm{min^{-1}}} \)

    \( \displaystyle t_{1/2}=69.3\,\mathrm{min} \)

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