Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: D and F Block Elements

Question:

The transition elements have incompletely filled d-subshells in their ground state or in any of their oxidation states. The transition elements occupy position in between s- and p-blocks in groups 3-12 of the Periodic table. Starting from fourth period, transition elements consists of four complete series : Sc to Zn, Y to Cd and La, Hf to Hg and Ac, Rf to Cn. In general, the electronic configuration of outer orbitals of these elements is (n - 1) d1-10 ns1-2. The electronic configurations of outer orbitals of Zn, Cd, Hg and Cn are represented by the general formula (n - 1)d10 ns2. All the transition elements have typical metallic properties such as high tensile strength, ductility, malleability. Except mercury, which is liquid at room temperature, other transition elements have typical metallic structures. The transition metals and their compounds also exhibit catalytic property and paramagnetic behaviour. Transition metal also forms alloys. An alloy is a blend of metals prepared by mixing the components. Alloys may be homogeneous solid solutions in which the atoms of one metal are distributed randomly among the atoms of the other.

Transition elements form alloys easily because they have which of the following properties?

Options:

Same atomic number

Same electronic configuration

Nearly same atomic size

Same oxidation states

Correct Answer:

Nearly same atomic size

Explanation:

Transition metals mix freely with each other in the molten state and on cooling a solution of different metals results in formation of alloy. The alloy formation is explained on the basis of similar sizes of atoms of these metals which allow the atoms of one metal to take up the positions in the crystal lattice of the other.