Target Exam

CUET

Subject

Chemistry

Chapter

Inorganic: Coordination Compounds

Question:

Which of the properties are shown by d-block elements  are shown by d-block elements?

A. Complex formation

B. Chelating agents

C. Bleaching agents

D. Catalytic agents

E. Alloy formation

Choose the correct answer from the options given below:

Options:

C, D, E only

A, B, C only

B, C, D only

A, D, E only

Correct Answer:

A, D, E only

Explanation:

The correct answer is option 4. A, D, E only.

Let us delve into why the properties complex formation, catalytic activity, and alloy formation are characteristic of d-block elements, and why the other properties are less relevant.

A. Complex Formation :

d-block elements, or transition metals, have a unique ability to form complex compounds due to their partially filled d-orbitals.

Coordination Chemistry: These metals can accept electron pairs from ligands (molecules or ions with lone pairs) to form coordination compounds. The metal acts as the central atom in these complexes.

Examples:

[Cu(NH₃)₄]²⁺: In this complex, copper(II) ion is surrounded by four ammonia molecules.

[Fe(CN)₆]⁴⁻: Iron(II) is surrounded by six cyanide ions.

Reason for Inclusion: The ability of d-block elements to form complexes is a fundamental property and is used extensively in various fields including chemistry, biology, and industrial applications.

D. Catalytic Agents:

d-block elements are widely recognized for their catalytic properties. They can alter the rate of chemical reactions without being consumed in the process. These metals can change their oxidation states, allowing them to facilitate redox reactions. They can form intermediate complexes with reactants, lowering the activation energy of reactions.

Examples:

Platinum (Pt): Used as a catalyst in hydrogenation reactions.

Palladium (Pd): Catalyzes various organic reactions, including cross-coupling reactions.

Reason for Inclusion: Catalytic activity is a hallmark of many d-block elements, making them invaluable in industrial and chemical processes.

E. Alloy Formation:

d-block elements are known for forming alloys with other metals. These alloys can have enhanced physical properties compared to the pure metals.

Examples:

Steel: An alloy of iron (a d-block element) and carbon. It has improved strength and durability compared to pure iron.

Bronze: An alloy of copper (a d-block element) and tin, known for its hardness and resistance to corrosion.

Reason for Inclusion: The ability of d-block elements to form alloys is significant in materials science and engineering, contributing to their industrial importance.

Properties that are Not Included are:

B. Chelating Agents:

Chelating agents are compounds that can form multiple bonds with a single metal ion, stabilizing it in solution.

Example: EDTA (ethylenediaminetetraacetic acid) is a chelating agent that forms complexes with d-block metals like iron and copper.

Reason for Exclusion: Chelating agents are not d-block elements themselves; rather, they interact with d-block metals. Therefore, this property is not characteristic of d-block elements but of compounds that can form complexes with them.

C. Bleaching Agents :

Bleaching agents are chemicals that remove color from materials, often through oxidation.

Examples: Chlorine (Cl₂) and hydrogen peroxide (H₂O₂) are common bleaching agents.

Reason for Exclusion: While some transition metal compounds can act as bleaching agents in specific contexts (e.g., certain metal oxides), this is not a primary or widespread property of d-block elements. Bleaching is more commonly associated with non-metallic oxidizing agents

Conclusion:
The properties complex formation, catalytic activity, and alloy formation are intrinsic characteristics of d-block elements due to their electronic structure and chemical behavior. Chelating agents and bleaching agents, while related to d-block chemistry, do not represent inherent properties of the d-block elements themselves. Thus, the correct choice reflects the fundamental and most characteristic properties of d-block elements: option 4: A, D, E only.