Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Biomolecules

Question:

n-Hexane is obtained when glucose is

Options:

Prolonged heated with HI

Reacted with hydroxylamine.

Treated with mild oxidising agent like bromine water.

Treated with acetic anhydride.

Correct Answer:

Prolonged heated with HI

Explanation:

The correct answer is Option (1) → Prolonged heated with HI

  • When glucose is prolongedly heated with hydroiodic acid (HI), it undergoes reductive cleavage.
  • All hydroxyl groups (–OH) in glucose are replaced by hydrogen atoms, resulting in the formation of an alkane with the same number of carbon atoms as glucose.
  • Glucose has 6 carbon atoms → the product is n-hexane.

Other options:

  • Hydroxylamine → forms oximes.
  • Bromine water → mild oxidation of aldehyde to acid.
  • Acetic anhydride → forms acetate esters.