How much current is needed to pass for 1 sec for depositing a metal with a mass equal to double of its electrochemical equivalent? |
1 amp 2 amp 4 amp 0.5 amp |
2 amp |
The correct answer is Option (2) → 2 amp According to Faraday’s first Law of Electrolysis: The amount of chemical reaction which occurs at any electrode during electrolysis by a current is proportional to the quantity of electricity passed through the electrolyte (solution or melt). m = Zit where, m = mass of substance deposited Z = electrochemical equivalent I = current in ampere t = time in secs To deposit a metal with mass equal to double of its electrochemical equivalent, it is given m = 2 × Z t = 1 sec substituting these values in equation m = Zit 2 × Z = Z × I × 1 Solving this we get, I (current needed) = 2 amp |