The correct increasing reactivity order for $S_N2$ reaction for the following compounds (A) Benzyl Chloride Choose the correct answer from the options given below: |
(A), (B), (D), (C) (A), (B), (C), (D) (A), (D), (C), (B) (B), (C), (D), (A) |
(A), (D), (C), (B) |
The correct answer is Option (3) → (A), (D), (C), (B) $\text{SN}_2$ reactivity is governed by steric hindrance (bulkiness). The reaction needs a clear path for a ''backside attack.'' Less bulk = faster reaction. (A) Benzyl (1°): Also has low bulk, but it's even faster than methyl. The adjacent benzene ring helps stabilize the transition state, lowering the reaction's energy.(Most Reactive) (B) Methyl: Least bulky (only small H atoms). Very fast $\text{SN}_2$. (C) Isopropyl (2°): Very bulky. Very slow $\text{SN}_2$. (D) Tertiary butyl (3°): Most bulky. No $\text{SN}_2$ reaction. (Least Reactive) |