Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Haloalkanes and Haloarenes

Question:

Statement I: Nitration of chlorobenzene leads to the formation of m-nitrochlorobenzene

Statement II: −NO2 group is a m-directing group

 

Options:

Both statement I and statement II are correct and statement II is the correct explanation of statement I

Both statement I and statement II are correct but statement II is not the correct explanation of statement I

Statement I is correct but statement II is false

Statement I is false but statement II is correct

Correct Answer:

Statement I is false but statement II is correct

Explanation:

Statement I: Nitration of chlorobenzene leads to the formation of m-nitrochlorobenzene.

This statement is false. Nitration of chlorobenzene typically results in the formation of a mixture of ortho (o-) and para (p-) nitrochlorobenzene isomers. The m-nitrochlorobenzene isomer is not the major product obtained in the nitration of chlorobenzene.

Statement II: -NO2 group is a m-directing group.

This statement is correct. The -NO2 group is known as a meta-directing group in electrophilic aromatic substitution reactions. It directs incoming groups or substitutions to the meta position on the aromatic ring.

Therefore, the correct answer is: 4. Statement I is false but statement II is correct.