Target Exam

CUET

Subject

Chemistry

Chapter

Organic: Aldehydes, Ketones and Carboxylic Acids

Question:

Which of the following is the best reducing agent to convert $RCOOH$ into $RCH_2OH$?

Options:

$LiBH_4$

$B_2H_6$

$NaBH_4$

Hydrogen in presence of Pd

Correct Answer:

$B_2H_6$

Explanation:

The correct answer is Option (2) → $B_2H_6$

To reduce a carboxylic acid (RCOOH) to a primary alcohol (RCH₂OH), a strong reducing agent is required.

    • NaBH₄ → too mild; does not reduce carboxylic acids,  reduces aldehydes and ketones only

    • LiBH₄ → stronger than NaBH₄ but still not effective for RCOOH

    • H₂ / Pd → does not reduce carboxylic acids to alcohols

    • B₂H₆ → specifically and efficiently reduces RCOOH → RCH₂OH