Number of coulombs required for the reduction of \(1 \text{ mol}\) of \(MnO_4^-\) to \(Mn^{2+}\) is :
Answer & explanation
Correct answer: option 2
The correct answer is Option (2) → \(4.825 × 10^5 C\)
By Faraday’s laws, the charge needed for a reduction is the number of moles of electrons taken up multiplied by the Faraday constant, F = 96500 C mol−1 (the charge on one mole of electrons).
In \( \ce{MnO4^{-}} \), x + 4(−2) = −1, so Mn is +7. Reduction to \( \ce{Mn^{2+}} \) therefore takes 7 − 2 = 5 electrons:
\( \ce{MnO4^- + 8H^+ + 5e^- -> Mn^2+ + 4H2O} \)
\( Q = 5 \times 96500\ \mathrm{C} = 482500\ \mathrm{C} = 4.825 \times 10^5\ \mathrm{C} \)
So 4.825 × 105 C (5 F) are needed for 1 mol of \( \ce{MnO4^{-}} \).
Note: This question is from NCERT (2026-27). NTA sets numerical questions from NCERT too, so do not ignore NCERT while practising numericals.
NCERT (2026-27 edition):
Exercises – “2.12 How much charge is required for the following reductions: … (iii) 1 mol of MnO4– to Mn2+?”