Practicing Success

Target Exam

CUET

Subject

Chemistry

Chapter

Physical: Chemical Kinetics

Question:

The half-life for the first order decomposition of nitramide is 2.1 hours at 15oC.

NH2NO2 (s) → N2O(g) + H2O(l)

If 6.2 g of NH2NO2 is allowed to decompose, calculate the time taken for 99% decomposition of NH2NO2.

Options:

12.95 hours

13.95 hours

14.95 hours

15.95 hours

Correct Answer:

13.95 hours

Explanation:

k = \(\frac{2.303}{t}\)log\(\frac{A_o}{A}\)

Initial moles of nitramide = \(\frac{6.2}{62}\) = 0.1

∴ t = \(\frac{2.303 × 2.1}{0.693}\)log\(\frac{0.1}{0.001}\) = 13.95 hour